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Results 1 to 25 of 80

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Kinetics of solvent exchange reactions at high pressureMERBACH, A. E.NATO ASI series. Series C, Mathematical and physical sciences. 1987, Vol 197, pp 311-331Conference Paper

The reaction volume for the equilibria between the lanthanide(III) ennea- and octaaqua ions as a diagnostic aid for their water-exchange mechanismsLAURENCZY, G; MERBACH, A. E.Helvetica chimica acta. 1988, Vol 71, Num 8, pp 1971-1973, issn 0018-019XArticle

Aqueous catalytic dimerisation of ethylene : characterization of the reaction intermediates [Ru(CH2=CH2)(H2O)5](tos)2 and [Ru(CH2=CH2)2(H2O)4](tos)2 (tos = toluene p-sulfonate)LAURENCZY, G; MERBACH, A. E.Journal of the Chemical Society. Chemical communications. 1993, Num 2, pp 187-189, issn 0022-4936Article

The binding of dinitrogen to ruthenium(II) in aqueous solutionLAURENCZY, G; HELM, L; MERBACH, A. E et al.Inorganica chimica acta. 1991, Vol 189, Num 2, pp 131-133, issn 0020-1693Article

A variable-pressure 2D 1H-NMR study of the mechanism of trimethyl phosphate intermolecular exchange and cis/trans-isomerisation of tetrachlorobis(trimethyl phosphate)zirconium(IV)FREY, U; HELM, L; MERBACH, A. E et al.Helvetica chimica acta. 1990, Vol 73, Num 1, pp 199-202, issn 0018-019X, 4 p.Article

Variable-pressure kinetic study of formation and dissociation of octahedral divalent metal ion monocomplexes in N,N-dimethylformamide: dissociative reaction mechanisms through the first row from manganese to nickelDUCOMMUN, Y; NICHOLS, P. J; MERBACH, A. E et al.Inorganic chemistry (Print). 1989, Vol 28, Num 13, pp 2643-2647, issn 0020-1669Article

Variable-pressure study of a molybdenum(III) reaction: first definitive evidence for the associative nature complex formation on hexaaquamolybdenum(III)RICHENS, D. T; DUCOMMUN, Y; MERBACH, A. E et al.Journal of the American Chemical Society. 1987, Vol 109, Num 2, pp 603-604, issn 0002-7863Article

High-pressure stopped-flow study of the complexation of vanadium(II) with thiocyanate in water: further evidence for the associative character of substitution on this metal ionNICHOLS, P. J; DUCOMMUN, Y; MERBACH, A. E et al.Inorganic chemistry (Print). 1983, Vol 22, Num 26, pp 3993-3995, issn 0020-1669Article

17O nuclear magnetic resonance in aqueous solutions of Cu2+ : the combined effect of Jahn-Teller inversion and solvent exchange on relaxation ratesPOWELL, D. H; HELM, L; MERBACH, A. E et al.The Journal of chemical physics. 1991, Vol 95, Num 12, pp 9258-9265, issn 0021-9606Article

N-N-dimethylformamide exchange on hexakis(N,N-dimethylformamide)titanium(III) : a variable-temperature and -pressure 1H and 17O NMR studyDELLAVIA, I; HELM, L; MERBACH, A. E et al.Inorganic chemistry (Print). 1992, Vol 31, Num 11, pp 2230-2233, issn 0020-1669Article

Adducts of titanium tetrahalides with neutral Lewis bases. II: Kinetics and reaction mechanism: a variable temperature and variable pressure proton NMR studyTURIN, E; NIELSON, R. M; MERBACH, A. E et al.Inorganica chimica acta. 1987, Vol 134, Num 1, pp 79-85, issn 0020-1693Article

Variable-temperature, -pressure, and -frequency oxygen-17 NMR study of water exchange on hexaaquatitanium(III): a limiting associative mechanism?HUGI, A. D; HELM, L; MERBACH, A. E et al.Inorganic chemistry (Print). 1987, Vol 26, Num 11, pp 1763-1768, issn 0020-1669Conference Paper

High pressure kinetics. A decisive dimension in mechanistic studies of inorganic reactionsVAN ELDIK, R; MERBACH, A. E.Comments on modern chemistry. Part A, Comments on inorganic chemistry. 1992, Vol 12, Num 6, pp 341-378, issn 0260-3594Article

Mechanisms of axial and equatorial dimethyl sulfoxide exchange on [TiO(DMSO)5]2+. A variable-temperature and -pressure 1H NMR studyDELLAVIA, I; HELM, L; MERBACH, A. E et al.Inorganic chemistry (Print). 1992, Vol 31, Num 20, pp 4151-4154, issn 0020-1669Article

Water-exchange mechanisms on the terbium to thulium octaaqualanthanide(III) ions: a variable-pressure 17O NMR studyCOSSY, C; HELM, L; MERBACH, A. E et al.Inorganic chemistry (Print). 1989, Vol 28, Num 14, pp 2699-2703, issn 0020-1669, 5 p.Article

High-pressure kinetic study of formation and dissociation of first- and second-row d10 divalent metal ion complexes with bipyridine in aqueous solution: a cation size dependent reaction mechanismDUCOMMUN, Y; LAURENCZY, G; MERBACH, A. E et al.Inorganic chemistry (Print). 1988, Vol 27, Num 7, pp 1148-1152, issn 0020-1669Article

Adducts of titanium tetrahalides with neutral Lewis bases. I: Structure and stability: a vibrational and multinuclear NMR studyTURIN, E; NIELSON, R. M; MERBACH, A. E et al.Inorganica chimica acta. 1987, Vol 134, Num 1, pp 67-78, issn 0020-1693Article

Water exchange on hexaaquavanadium(III): a variable-temperature and variable-pressure 17O-NMR study at 1.4 and 4.7 teslaHUGI, A. D; HELM, L; MERBACH, A. E et al.Helvetica chimica acta. 1985, Vol 68, Num 2, pp 508-521, issn 0018-019XArticle

Monocomplex formation and dissociation of some first row divalent transition metal ions with 2-chloro-1,10-phenanthroline by the high-pressure stopped-flow techniqueLAURENCZY, G; BUGNON, P; MERBACH, A. E et al.Inorganica chimica acta. 1992, Vol 198200, pp 159-164, issn 0020-1693Article

Dimethylformamide-exchange mechanism on some first-row divalent transition-metal ionsCOSSY, C; HELM, L; MERBACH, A. E et al.Helvetica chimica acta. 1987, Vol 70, Num 6, pp 1516-1525, issn 0018-019XArticle

Activation parameters and mechanism for water exchange of tetraaquaplatinum(II) studied by high-pressure oxygen-17 NMR spectroscopyHELM, L; ELDING, L. I; MERBACH, A. E et al.Inorganic chemistry (Print). 1985, Vol 24, Num 11, pp 1719-1721, issn 0020-1669Article

Mechanism of dimethyl sulfide intermolecular exchange and trans-cis isomerization of SnCl4•2Me2S. Variable-pressure proton NMR and variable-temperature tin-119 magnetization transfer NMR studiesKNIGHT, C. T. G; MERBACH, A. E.Inorganic chemistry (Print). 1985, Vol 24, Num 4, pp 576-581, issn 0020-1669Article

Variable-pressure kinetic and equilibrium study of monocomplex formation of copper(II) and zinc(II) with 2-chloro-1,10-phenanthroline in aqueous solutionLAURENCZY, G; DUCOMMUN, Y; MERBACH, A. E et al.Inorganic chemistry (Print). 1989, Vol 28, Num 15, pp 3024-3028, issn 0020-1669Article

Variable-temperature and variable-pressure kinetic and equilibrium studies of formation and dissociation of [V(H2O)5NCS]2+SAUVAGEAT, P.-Y; DUCOMMUN, Y; MERBACH, A. E et al.Helvetica chimica acta. 1989, Vol 72, Num 8, pp 1801-1808, issn 0018-019XArticle

Oxygen-17 nuclear magnetic resonance kinetic study of water exchange on the lanthanide(III) aqua ionsCOSSY, C; HELM, L; MERBACH, A. E et al.Inorganic chemistry (Print). 1988, Vol 27, Num 11, pp 1973-1979, issn 0020-1669Article

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